At the critical point of a substance, which of the following is true?
Q.42Medium
For an ideal gas undergoing isothermal expansion from V₁ to V₂, the entropy change is:
Q.43Medium
The residual property in thermodynamics is defined as the difference between:
Q.44Medium
A process where temperature and pressure both increase is most likely:
Q.45Medium
The compressibility factor Z for a real gas at high pressures typically:
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Q.46Easy
In a constant volume process, the heat added to the system equals:
Q.47Medium
The partial molar volume of a component in solution is:
Q.48Medium
For a binary ideal solution at constant T and P, the Gibbs energy of mixing is:
Q.49Easy
A system absorbs 500 J of heat and does 200 J of work on surroundings. The change in internal energy is:
Q.50Medium
The virial equation of state truncated after second term is: PV = nRT(1 + B(T)P/RT). What does B(T) represent?
Q.51Medium
For a reversible process in an isolated system, the entropy change is:
Q.52Medium
An engineering application of throttling includes:
Q.53Hard
The osmotic pressure of a dilute solution is given by van't Hoff equation: π = iMRT. What does 'i' represent?
Q.54Hard
When CO₂ gas at 1 atm is cooled below the sublimation temperature (~195 K), it directly converts to dry ice without passing through liquid phase. This phenomenon is explained by:
Q.55Hard
For a real gas obeying virial equation PV/nRT = 1 + B/V̄, the internal energy change with volume at constant T is:
Q.56Hard
In a Joule-Thomson expansion of real gas at 298 K, a positive μ_JT (inversion coefficient) means:
Q.57Easy
At constant temperature and pressure, which of the following represents the Gibbs free energy change for a spontaneous process?
Q.58Easy
The Clausius-Clapeyron equation relates vapor pressure to temperature. Which statement is correct?
Q.59Easy
For an ideal gas undergoing adiabatic compression, the entropy change is:
Q.60Easy
In a constant pressure process, the heat absorbed by a system equals: